Publications and Patents

Catalysts Design and Synthesis of Homogeneous Oxidation Catalysts

  • Zebrafish Assays as Developmental Toxicity Indicators in the Green Design of TAML Oxidation Catalysts. L. Truong, M. A. DeNardo, S. Kundu, T. J. Collins, and R. L. Tanguay, Green Chemistry, 2013, 15(9), 2339-2343, DOI:10.1039/C3GC40376A.
  • Designing endocrine disruption out of the next generation of chemicals, T. T. Schug, R. Abagyan, B. Blumberg, T. J. Collins, D. Crews, P. L. DeFur, S. M. Dickerson,T. M. Edwards, A. C. Gore, L. J. Guillette, T. Hayes, J. J. Heindel, A. Moores, H. B. Patisaul, T. L. Tal, K. A. Thayer, L. N. Vandenberg, J. C. Warner, C. S. Watson, F. S. vom Saal, R. T. Zoeller, K. P. O'Brien, and J. P. Myers, Green Chem., 2013,15, 181-19, DOI: 10.1039/c2gc350
  • Ellis, W. C.; Tran, C. T.; Roy, R.; Rusten, M.; Fischer, A.; Ryabov, A. D.; Blumberg, B.; Collins, T. J. Designing Green Oxidation Catalysts for Purifying Environmental Waters, J. Am. Chem. Soc., 2010, 132(28), 9774–9781.
  • Ellis, W. C.; Tran, C. T.; DeNardo, M. A.; Fischer, A.; Ryabov, A. D.; Collins, T. J., Design of More Powerful Iron-TAML Peroxidase Enzyme Mimics, J. Am. Chem. Soc., 2009, 131(50), 18052–18053.
  • Popescu, D.-L.; Chanda, A.; Stadler, M. J.; Mondal, S.; Tehranchi, J.; Ryabov, A. D.; Collins, T. J., Mechanistically Inspired Design of Fe(III)TAML Peroxide-Activating Catalysts, J. Am. Chem. Soc. 2008, 130(13), 4497–4506.
  • Tiago de Oliveira, F.; Chanda, A.; Banerjee, D.; Shan, X.; Mondal, S.; Que, L., Jr.; Bominaar, E. L.; Münck, E.; Collins, T. J., Chemical and Spectroscopic Evidence for an FeV-Oxo Complex. Science 2007, 315(5813), 835-838 (abstract) (full text).
  • Ghosh, A.; Tiago de Oliveira, F.; Yano, T.; Nishioka, T.; Beach E. S.; Kinoshita, I.; Münck, E.; Ryabov, A. D.; Horwitz, C. P.; Collins, T. J. Catalytically active μ-Oxodiiron(IV) oxidants from Iron(III) and dioxygen. J. Am. Chem. Soc. 2005, 127(8), 2505-13 (abstract).
  • Patterson, R. E.; Gordon-Wylie, S. W.; Woomer, C. G.; Norman, R. E.; Weintraub, S. T.; Horwitz, C. P.; Collins, T. J. Electron-Transfer Oxidation by Phase-Separating Reagents. Inorg. Chem. 1998, 37(18), 4748-4750.
  • Miller, C. G.; Gordon-Wylie, S. W.; Horwitz, C. P.; Strazisar, S. A.; Peraino, D. K.; Clark, G. R.; Weintraub, S. T.; Collins, T. J. A Method for Driving O-Atom Transfer: Secondary Ion Binding to a Tetraamide Macrocyclic Ligand. J. Am. Chem. Soc. 1998, 120(44), 11540-11541.
  • Horwitz, C. P.; Fooksman, D. R.; Vuocolo, L. D.; Gordon-Wylie, S. W.; Cox, N. J.; Collins, T. J. Ligand design approach for securing robust oxidation catalysts. J. Am. Chem. Soc. 1998, 120(19), 4867-4868.
  • Bartos, M. J.; Gordon-Wylie, S. W.; Fox, B. G.; Wright, L. J.; Weintraub, S. T.; Kauffmann, K. E.; Münck, E; Kostka, K. L.; Uffelman, E. S.; Rickard, C. E. F.; Noon, K. R.; Collins, T. J. Designing Ligands to Achieve Robust Oxidation Catalysts, Coord. Chem. Rev. 1998, 174, 361–390.
  • Collins, T. J.; Bartos, M. J.; Gordon-Wylie, S. W.; Fox, B. G.; Kauffmann, K. E.; Münck, E.; Rickard, C. E. F.; Weintraub, S. T.; Uffelman, E. S.; Wright, L. J. Designing ligands to achieve robust atom-transfer oxidation catalysts, J. Inorg. Biochem. 1995, 59, 318.
  • Gordon-Wylie, S. W.; Blanton, W. H.; Claus, B. L.; Horwitz, C. P.; Collins, T. J. Towards magnetic Building Blocks: Synthesis of a planar Co(III)—cation radicalCo(III)—Complex of the binucleating ligand 1,2,4,5-tetrakis(2-hydroxy-2-methylpropanamido)benzene, Inorg. Synth., 2002, 33, Ch. 1, 1–10.
  • Gordon-Wylie, S. W.; Claus, B. L.; Horwitz, C. P.; Leychkis, Y.; Workman, J. M.; Marzec, A. J.; Clark, G. R.; Rickard, C. E. F.; Conklin, B. J.; Sellers, S.; Yee, G. T.; Collins, T. J. New magnetically coupled bimetallic complexes as potential building blocks for magnetic materials. Chem. Eur. J. 1998, 4(11), 2173-2181.
  • Gordon-Wylie, S. W.; Bominaar, E. L.; Collins, T. J.; Workman, J. M.; Claus, B. L.; Patterson, R. E.; Williams, S. A.; Conklin, B. J.; Yee, G. T.; Weintraub, S. T. Ligand design for securing ferromagnetic exchange coupling in multimetallic complexes. Chem. Eur. J. 1995, 1(8), 528-537.
  • Glatzel, P.; Bergmann, U.; Gu, W.; Wang, H.; Stepanov, S.; Mandimutsira, B. S.; Riordan, C.; Horwitz, C. P.; Collins, T. J.; Cramer, S. P., Electronic structure of Ni Complexes by X-ray resonance raman spectroscopy (Resonant inelastic X-ray scattering). J. Am. Chem. Soc. 2002, 124(33), 9668-9669.
  • Horwitz, C. P.; Gordon-Wylie, S. W.; Leychkis, Y.; Flynn, D. M.; Weintraub, S. T.; Clark, G. R.; Collins, T. J. Modifying the chemistry of a macrocyclic cobalt complex by remote site manipulation. J. Phys. Chem. B 2001, 105(37), 8821-8828.
  • Bartos, M. J.; Kidwell, C.; Kauffmann, K. E.; Gordon-Wylie, S. W.; Collins, T. J.; Clark, G. C.; Münck, E.; Weintraub, S. T., A stable aquairon(III) complex with S = 1: structure and spectroscopic properties. Angew. Chem., Int. Ed. Engl. 1995, 34(11), 1216-1219.
  • Kostka, K. L.; Fox, B. G.; Hendrich, M. P.; Collins, T. J.; Rickard, C. E. F.; Wright, L. J.; Münck, E. High-valent transition metal chemistry. Mössbauer and EPR studies of high-spin (S = 2) iron(IV) and intermediate-spin (S = 3/2) iron(III) complexes with a macrocyclic tetraamido-N ligand. J. Am. Chem. Soc. 1993, 115(15), 6746-6757.
  • Workman, J. M.; Powell, R. D.; Procyk, A. D.; Collins, T. J.; Bocian, D. F. Vibrational and electrochemical properties of a series of stable manganese(V)-oxo complexes. Inorg. Chem. 1992, 31(9), 1548-1550.
  • Collins, T. J.; Fox, B. G.; Hu, Z. G.; Kostka, K. L.; Münck, E.; Rickard, C. E. F.; Wright, L. J. High valent transition metal chemistry. Synthesis and characterization of an intermediate-spin iron(IV) complex of a strong pi-acid ligand. J. Am. Chem. Soc. 1992, 114(22), 8724-6725.
  • Collins, T. J.; Powell, R. D.; Slebodnick, C.; Uffelman, E. S. Stable highly oxidizing cobalt complexes of macrocyclic ligands. J. Am. Chem. Soc. 1991, 113(22), 8419-8425.
  • Collins, T. J.; Nichols, T. R.; Uffelman, E. S. A square-planar nickel(III) complex of an innocent ligand system. J. Am. Chem. Soc. 1991, 113(12), 4708-4709.
  • Collins, T. J.; Kostka, K. L.; Uffelman, E. S.; Weinberger, T. L. Design, synthesis, and structure of a macrocyclic tetraamide that stabilizes high-valent middle and later transition metals. Inorg. Chem. 1991, 30(22), 4204-4210.
  • Collins, T. J.; Slebodnick, C.; Uffelman, E. S. Chromium(V)-oxo complexes of macrocyclic tetraamido-N ligands tailored for highly oxidized middle transition metal complexes: a new oxygen-18-labeling reagent and a structure with four nonplanar amides. Inorg. Chem. 1990, 29(18), 3433-3436.
  • Collins, T. J.; Powell, R. D.; Slebodnick, C.; Uffelman, E. S. A water-stable manganese(V)-oxo complex: definitive assignment of a MnV=O infrared vibration. J. Am. Chem. Soc. 1990, 112(2), 899-901.
  • Collins, T. J.; Kostka, K. L.; Münck, E.; Uffelman, E. S. Stabilization of mononuclear five-coordinate iron(IV). J. Am. Chem. Soc. 1990, 112(14), 5637-5639.
  • Collins, T. J.; Workman, J. M. Nonplanar amido groups only through carbon-nitrogen bond twisting. Angew. Chem. 1989, 101(7), 924-925.
  • Collins, T. J.; Uffelman, E. S. A nonplanar amide group in ligands: the first macrocyclic square planer cobalt(III) complex. Angew. Chem. 1989, 101(11), 1552-1554.
  • Collins, T. J.; Gordon-Wylie, S. W. A manganese(V)-oxo complex. J. Am. Chem. Soc. 1989, 111(12), 4511-4513.
  • Brewer, J. C.; Collins, T. J.; Smith, M. R.; Santarsiero, B. D. Neutral square planar cobalt(III) complexes. J. Am. Chem. Soc. 1988, 110(2), 423-428.
  • Collins, T. J.; Lai, T.; Peake, G. T., A novel nonplanar amido-N ligand type. Nonplanarity in the amido-N ligand induced by steric effects. Inorg. Chem. 1987, 26(11), 1674-1677.
  • Anson, F. C.; Collins, T. J.; Richmond, T. G.; Santarsiero, B. D.; Toth, J. E.; Treco, B. G. R. T. Highly stabilized copper(III) complexes. J. Am. Chem. Soc. 1987, 109(10), 2974-2979.
  • Anson, F. C.; Collins, T. J.; Gipson, S. L.; Krafft, T. E., Alcohol electrooxidation catalysts from degraded polyanionic chelating ligand complexes. The uncertainty for catalyst identification that accompanies a decomposing catalytic system. Inorg. Chem. 1987, 26(5), 731-736.
  • Anson, F. C.; Collins, T. J.; Gipson, S. L.; Keech, J. T.; Krafft, T. E. Electrochemical studies of reactive polyanionic chelating ligand complexes in liquid sulfur dioxide. Formation of highly oxidizing inorganic complexes. Inorg. Chem. 1987, 26(7), 1157-1160.
  • Anson, F. C.; Collins, T. J.; Coots, R. J.; Gipson, S. L.; Krafft, T. E.; Santarsiero, B. D.; Spies, G. H. Oxidative and hydrolytic decomposition of a polyanionic chelating ligand. Inorg. Chem. 1987, 26(7), 1161-1168.
  • Collins, T. J.; Richmond, T. G.; Santarsiero, B. D.; Treco, B. G. R. T., Paramagnetic cobalt(III) complexes of polyanionic chelating ligands. J. Am. Chem. Soc. 1986, 108(8), 2088-2090.
  • Collins, T. J.; Coots, R. J.; Furutani, T. T.; Keech, J. T.; Peake, G. T.; Santarsiero, B. D. Nonplanar amide groups as ligands. J. Am. Chem. Soc. 1986, 108(17), 5333-5339.
  • Barner, C. J.; Collins, T. J.; Mapes, B. E.; Santarsiero, B. D. Reactions of osmium(IV) complexes of PAC ligands with azide species. Inorg. Chem. 1986, 25(24), 4322-4323.
  • Anson, F. C.; Collins, T. J.; Gipson, S. L.; Keech, J. T.; Krafft, T. E.; Peake, G. T. Interconversion of planar and nonplanar N-amido ligands. Thermodynamically stable nonplanar N-amido ligands. J. Am. Chem. Soc. 1986, 108(21), 6593-6605.
  • Christie, J. A.; Collins, T. J.; Krafft, T. E.; Santarsiero, B. D.; Spies, G. H. Complexation of a tetradentate tetraanionic ligand to osmium(IV): a step towards the development of multianionic chelating ligands for use in stabilizing oxidizing inorganic complexes. J. Chem. Soc., Chem. Commun. 1984, (3), 198-199.
  • Anson, F. C.; Collins, T. J.; Coots, R. J.; Gipson, S. L.; Richmond, T. G. Synthesis and characterization of stable cobalt(IV) coordination complexes: molecular structure of trans-[h4-1,2-bis(3,5-dichloro-2-hydroxybenzamido)-4,5-dichlorobenzene]bis(4-tert-butylpyridine)cobalt(IV). J. Am. Chem. Soc. 1984, 106(17), 5037-5038.
  • Anson, F. C.; Christie, J. A.; Collins, T. J.; Coots, R. J.; Furutani, T. T.; Gipson, S. L.; Keech, J. T.; Krafft, T. E.; Santarsiero, B. D.; Spies, G. H. The design of multianionic chelating ligands for the production of inorganic oxidizing agents. Osmium coordination chemistry that provides stable potent oxidizing agents and stable potent reducing agents. J. Am. Chem. Soc. 1984, 106(16), 4460-4472.